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Quantum Physics Timeline

This timeline traces the developments in quantum physics from 1900 to around 1930.

The period from 1900 to 1930 was the period during which quantum physics was born. Throughout that time, there were many scientists who contributed to our current understanding of quantum mechanics.

To view a particular scientist's contribution, click their name. To view a more detailed explanation of their discovery, click the discovery link.

 

 

 

Scientists:

Main Contributors:

Johannes Rydberg

Ernest Rutherford

Albert Einstein

Niels Bohr

James Chadwick

Louis de Broglie

Wolfgang Pauli

Werner Heisenberg

Enrico Fermi

Clinton Davisson

Lester Germer

 

Other Contributors:

JJ Thomson, Max Planck, Hans Geiger, Ernest Marsden, James Franck, Gustav Hertz, E.S. Bieler, Satyenda Nath Bose, Max Born, Pascual Jordan, Erwin Schrödinger, Paul Dirac and George Paget Thomson.

 

Timeline:

Year

Development

1897

Joseph John Thomson discovers the electron.

1898

JJ Thomson follows on from his discovery of the electron to develop his “plum pudding” model of the atom.

1900

Johannes Rydberg refines the expression for observed hydrogen line spectrums.

1900

Max Planck explains black body radiation using quantized energy emissions. Quantum theory is born. He postulated that energy is released in small packets, which he termed quanta.

1901

Max Planck defined Planck’s constant and published his quantum theory.

1903

Ernest Rutherford established that alpha particles have a positive charge.

1905

Albert Einstein releases his theory of special relativity. He also explained the photoelectric effect, determined the mass-energy equivalence and proposed that light consists of discrete quantized bundles of energy. These later become known as photons.

1908

The Paschen series in hydrogen atoms is discovered.

1908

Hans Geiger develops the Geiger counter, a device that can measure radiation.

1909

Ernest Rutherford and Thomas Royds demonstrate that alpha particles are doubly ionized helium atoms.

1909

Hans Geiger and Ernest Marsden conduct the Geiger-Marsden experiment where they fire alpha particles at metal foils. The results contradict current theories.

1911

Ernest Rutherford explains the result from the Geiger-Marsden experiment and proposes his nuclear model of the atom.

1913

Niels Bohr proposes his nuclear model of the atom. He also proposes his idea of stationary energy states and accounts for the spectrum of hydrogen.

1914

James Franck & Gustav Hertz confirmed the existence of stationary states through an electron scattering experiment.

1914

Ernest Rutherford proposes that the positively charged nucleus contains protons.

1914

James Chadwick shows that the primary beta-spectrum is continuous and shows an energy anomaly.

1916

The Lyman series of hydrogen is discovered.

1916

Albert Einstein develops the conservation of energy-momentum in general relativity.

1917

Albert Einstein introduces the idea of stimulated radiation emission.

1920

Ernest Rutherford predicts the existence of a neutron.

1921

James Chadwick and E.S. Bieler conclude that some strong force holds a nucleus together. They call this ‘strong nuclear interaction.’

1922

The Brackett series of hydrogen is discovered.

1923

Louis de Broglie generalises wave-particle duality by suggesting that particles have wave-like properties.

1924

The Pfund series of hydrogen is discovered.

1924

Satyenda Nath Bose and Albert Einstein find a new way to count quantum particles. This was later called Bose-Einstein statistics.

1925

Wolfgang Pauli explains the Zeeman effect and develops his quantum exclusion principle.

1925

Werner Heisenberg, Max Born and Pascual Jordan develop matrix mechanics. This was an initial step towards quantum field theory.

1926

Enrico Fermi and Paul Dirac find a second way to count quantum particles.

1926

Erwin Schrödinger develops a second description of quantum physics, called wave mechanics. He later proves this to equal Heisenberg's matrix mechanics.

1927

Clinton Davisson, Lester Germer and George Paget Thomson confirm the wavelike nature of electrons through electron diffraction by a crystal.

1927

Niels Bohr develops his principle of complemetarity.

1927

Heisenberg states his uncertainty principle. This states that it is impossible to measure the position and momentum of a particle at the same time.

1928

Paul Dirac presents a relativistic theory of the electron that includes the prediction of an anti-electron.

1930

Erwin Schrödinger predicts the zitterbewegung motion effect.

1932

James Chadwick discovers the neutron.

1932 onwards

The Future

 


Individual Discoveries:

Discovery of the Electron:

1897 - Joseph John Thomson, a knighted British physicist, investigated cathode rays and identified that they were made up of a stream of negatively charged particles. These become known as electrons. He also measured an electron's mass to be around 1000 times smaller than that of a hydrogen ion. Without first having knowledge of electrons, future developments and models would not have been possible.

 


The "Plum Pudding" Model:

1898 - J.J. Thomson continued on from his work with electrons to develop a model of the atom. This model became known as the "plum pudding" model. In the model, he described electrons as negative plums embedded in a pudding of positive matter.

 


Hydrogen Line Spectrums:

1900 - Johannes Rydberg, a Swedish Physicist, refined the expression for observed hydrogen line spectrums. However, at this time the phenomenon was still unexplainable. What Rydberg was witnessing was the Balmer series of hydrogen. The Balmer series was the spectra of lines consisting of visible light with transitions to the first excited state (n=2).

 


Black Body Radiation & the Birth of Quantum Theory:

1900 - American physicist Max Planck explains black body radiation in terms of an emission of quantized energy packets. He postulated that energy is radiated in small units. He called these units quanta. A black body is an object that absorbs all radiation that falls on it. Planck's law states that the spectral intensity of electromagnetic radiation from a black body at a certain temperature is given by an expression.

 

Planck would eventually receive the Nobel prize for this work and without this law, Einstein would not have been able to produce his report five years later on special relativity.

Planck did run in to one problem with his work. When Planck derived the black body radiation equation he made an assumption that energy was quantized. He had no way to prove this and so assumed that it was just a mathematical trick.

 


Planck's Constant & the Publication of Quantum Theory:

1901 - Max Planck calculated the value to Planck's constant to be 6.6260693 x 10-34 J s. He also published his quantum theory.

 


Alpha Particle Nature:

1903 - Ernest Rutherford, a New Zealand physicist, establishes the fact that alpha particles have a positive charge. This allowed for later scientists to establish alpha particles as helium nuclei.

 


Einstein's Theory of Special Relativity:

1905 - German born, Swiss/American physicist Albert Einstein released his theory of special relativity. Prior to this, the photoelectric effect required explaining. The photoelectric effect is the emission of electrons from matter upon the absorption of electromagnetic radiation. Einstein explained this by proposing that light consisted of discrete quantized bundles of energy. These were later called photons.

He also determined the mass-energy equivalence formula, and this became one of the most well known equations of all time.

E = mc2

 

He also stated that the speed of light was constant for all observers and that it was independent of its source.

The year of 1905 was later regarded as his "wonderful" year as it was the year he began to unravel more mysteries of physics than any other scientist.

 


The Geiger Counter:

1908 - Hans Geiger develops the Geiger counter, a device capable of detecting radiation. The device proved exceedingly useful for later experiments conducted using radioactive sources.

 


The Paschen Series:

1908 - The Paschen series of hydrogen was discovered. These were lines consisting of infra-red radiation with transitions to the second excited states (n=3).

 


Alpha Particles:

1909 - Ernest Rutherford and Thomas Royds demonstrated that alpha particles are doubly ionized helium atoms. This discovery would not have been made possible except for Rutherford's 1903 work on the nature of an alpha particle.

 


Geiger-Marsden Experiment:

1909 - From Rutherford's above work, Hans Geiger and Ernest Marsden undertook the Geiger-Marsden experiment whereby different metal foils were bombarded with alpha particles.

According to the prevailing "Plum pudding" model of the time, all the alpha particles should have been deflected off but only some were reflected.

This result meant that the "plum pudding" model of the atom was incorrect but it wasn't until 1911 that this result was explained.

 


Rutherford's Model of the Atom:

1911 - Following the disproven "plum pudding" model, Rutherford set out to propose his own model of the atom. Based on the results of the Geiger-Marsden experiment, he postulated that since only some alpha particles were deflected, the atom must be mainly empty space.

He concluded that most of the atom's mass was located in a tiny centre, the nucleus, and electrons were held in orbits surrounding this nucleus by electrostatic attraction.

But his new model was not fool proof. The main problem surrounding his model was that based on his predictions, electrons should radiate electromagnetic energy and rapidly spiral into the nucleus.

However, despite its obvious problems, the model provided the base for Bohr's work a few years later.

 


Bohr's Model of the Atom:

1913 - Following on from the model developed by Ernest Rutherford, Danish physicist Niels Bohr developed his own model of the atom. He followed on from Rutherford's idea that electrons orbited the nucleus but also stated that the chemical properties of an element were largely due to its electron configuration.

Bohr also introduced the idea that an electron could drop from a higher energy orbit to a lower one, emitting a photon of discrete energy. This was the main reason for its success, the fact that it could explain the spectral lines of hydrogen observed by Rydberg in 1900.

Bohr's model would not have been made possible without Rutherford's model before him and knowledge of the hydrogen spectrum.

A success of Bohr's model was that an equation was developed that could predict the wavelengths of hydrogen spectrum lines:

 

The model also correctly predicted the ionisation energy for hydrogen and predicted the existence of other series in the spectrum (even though they had not yet been discovered).
However, there was still limitations with the model. These included:

·     The Bohr model of the atom was only able to be exclusively applied to hydrogen. It failed to explain the behaviour of any atoms that contained more than one electron.

·     The Bohr model was unable to explain the observed trend that some spectral lines were more intense than others in the spectrum of hydrogen. In other words, it failed to explain why the hydrogen spectrum was inconsistent.

·     When the individual spectral lines were examined closely it was found that they were not solid lines of emitted light or a narrow range of frequencies emitted from the atom, but that they were in fact made up of a number of hyperfine spectral lines. This could not be explained by the Bohr model of the atom.

·    The Bohr model failed to explain the observation why a discharge tube, when placed in a magnetic field, caused the spectral lines to be split into several finely separated but individual lines. This became known as the Zeeman Effect. This implied the energy levels were split which was unacceptable to the concept of metastable orbits or energy levels in the Bohr model.

·     The model itself is a mixture of classical physics and quantum physics and this is a problem in itself.

 


Stationary States:

1914 - James Franck and Gustav Ludwig Hertz worked together to validate the Bohr model of the atom. Their experiment became known as the Franck-Hertz experiment and by performing an electron scattering experiment they were able to confirm the existence of stationary states.

 


Protons in the Nucleus:

1914 - Ernest Rutherford proposed that the nucleus, which was known to be positively charged, contained protons.

 


Continuous Primary Beta Spectrum:

1914 - Sir James Chadwick, and English physicist, showed that the primary beta spectrum is continuous but contains an energy anomaly.

 


The Lyman Series

1916 - The Lyman series of hydrogen was discovered. These were lines with ultraviolet radiation that had transitions to the ground state (n=1).

 


Conservation of energy-momentum:

1916 - Albert Einstein develops the theory for the conservation of momentum-energy for general relativity. He stated that momentum and energy are intertwined just as space and time are.

From this it follows that mass, energy and momentum will cause the space-time continuum to be curved.

 


Stimulated Radiation Emission:

1917 - Albert Einstein introduces the idea of stimulated radiation emission. This idea had implications in science for the future as stimulated radiation emission is what makes lasers possible.

 


Prediction of the Neutron:

1920 - Due to the fact that there was a mass difference in what an atom should weigh and its actual mass, Ernest Rutherford concluded that the nucleus of a atom contained some particle that had mass but no charge. He theoretically predicted the existence of the neutron.

This prediction later led to James Chadwick's confirmation of the existence of neutrons in 1932.

 


Strong Nuclear Interaction:

1921 - Due to the fact that the gravitational attraction of particles in the nucleus was not sufficient enough to hold a nucleus together and the fact that based on what was known at the time, a nucleus should fly apart, James Chadwick and E.S. Bieler conclude that some strong force holds a nucleus together. They called this force 'strong nuclear interaction.'

 


Brackett Series of Hydrogen:

1922 - The Brackett series of hydrogen was discovered. These were lines with infra-red radiation that had transitions to the third excited state (n=4).

 


Wave-Particle Duality:

1923 - French nobleman and physicist, Louis de Broglie, concluded that because no-one had successfully proven light was a wave or a particle, all particles must have some wave-like properties and vice versa.

His greatest achievement was to take this idea and development it mathematically into a formula. The de Broglie wavelength of a particle could be expressed by:

However, de Broglie had no experimental results to back up his conclusions and so it was not readily accepted.


Discovery of the Pfund Series:

1924 - The Pfund series of hydrogen , consisting of infra red lines with transitions to the fourth excited state (n=5), is discovered.

 


Bose-Einstein Statistics:

1924 - Satyenda Nath Bose and Albert Einstein combined together to find a new way to count quantum particles. This later became known as Bose-Einstein statistics. They also predicted that extremely cold atoms should condense into a single quantum state. This later became known as the Bose-Einstein condensate.

 


Quantum Exclusion Principle:

1925 - Wolfgang Pauli, an Austrian physicist, is most noted for his work on the quantum exclusion principle. He also explained the previously unexplainable Zeeman effect.

Pauli stated that electrons, known as fermions in his principle, are unable to occupy the same quantum state. As a result of this electrons 'pile on top' of one another and this can produces phenomena such as the Zeeman effect.

Pauli used Bohr's model of the atom that electrons were contained in shells and realised that by adding a fourth quantum number to where there was only three before, he could explain the maximum number of electrons in each shell.

The exclusion principle provided the reason as to why electrons were arranged in shells of 2, 8, 18, etc.

 


Matrix Mechanics:

1925 - German physicists Werner Heisenberg, Max Born and Pascual Jordan successfully developed matrix mechanics. Matrix mechanics was the first version of quantum mechanics and lead to the development of quantum field theory. They built a 'coherent mathematical framework' to which quantum physics could be applied.

From this, Wolfgang Pauli applied matrix mechanics to the hydrogen atom and successfully derived Balmer's equation and Rydberg's constant.

 


Fermi-Dirac Statistics:

1926 - Enrico Fermi and Paul Dirac find a second method to count quantum particles. The became known as Fermi-Dirac statistics and opened the way for solid-state physics. Through this, Fermi discovers the spin-statistics connection.

 


Wave Mechanics:

1926 - Erwin Schrödinger develops a second description of quantum mechanics. He calls his description wave mechanics and is based more on physical, continuous wave motions whereas Heisenberg's was based on a mathematical approach. Schrödinger's definition included the famous Schrödinger equation:

 

Heisenberg did not like Schrödinger's more practical approach but later in the year Schrödinger proved that the two descriptions were equal. He showed that Heisenberg's matrices could be developed in his own theory and that his own theory could be derived from Heisenberg's matrices.

 


Heisenberg's Uncertainty Principle:

1927 - Werner Heisenberg develops his uncertainty principle. Heisenberg showed that uncertainty is an inherent property of quantum mechanics. He reasoned that there were pairs of quantities that could not be determined simultaneously. He stated that if a particle's exact position is known, its momentum cannot be known accurately and vice versa.

This is represented by Heisenberg's Uncertainty Principle where ∆x and ∆p are inherent uncertainties in position and momentum:


Principle of Complementarity:

1927 - Niels Bohr was not entirely happy with Heisenberg's Uncertainty Principle. It was based on wave-particle duality and the fact that an observation of an atomic system would disturb the system. Bohr preferred the description put forward in his principle of complemetarity in that when you observe a wave-like property of something, it still has a particle-like nature but you do not see it during the observation. This rule also holds true for the inverse.

 


Wave-like Nature of Electrons:

1927 - Clinton Davisson and Lester Germer  confirmed the wavelike nature of an electron independently of George Paget Thomson, who did likewise. They did this by verifying the electron diffraction of a crystal.

Davisson & Germer were actually trying to study the reflection of electrons from a nickel surface. However, there was a crack in the vacuum tube they were using and as a result the nickel surface oxidised. They attempted to remove the oxidisation by heating, but this recrystallised the surface. When they fired electrons at it now, the electrons were diffracting. Since diffraction is a wave property they had almost inadvertently proven de Broglie's theory.

 


The Dirac Equation:

1928 - Paul Dirac presented a relativistic theory of an electron. This included the Dirac Equation which could correctly predict the spin of electrons. He also predicted the existence of a particle similar to an electron but one that had a positive charge. An anti-electron, or positron, was observed by Carl Anderson in 1932.

 


The Zitterbewegung Motion:

1930 - Erwin Schrödinger proposed his concept of zitterbewegung motion. The motion is a theoretical circular motion formula for elementary particles, in particular electrons. This motion is responsible for producing their spin and magnetic moment.

 


Discovery of the Neutron:

1932 - James Chadwick discovered the neutron. After years of predicted existence since being put forward in 1920 by Ernest Rutherford, the final frontier in terms of atomic understanding was complete and this discovery marked the end of the development of quantum physics but the beginning of its wider reach.

 


The Future:

Following Chadwick’s discovery, a new and exciting world became possible through quantum physics.

Over the ensuing years quantum mechanics had a big impact on developments in technology. These included:

-     The ability to explain and control properties in metals, insulators, semiconductors and superconductors.

·     The invention of the transistor. This invention led to more developments in the areas of computing and micro chipping. It also led a revolution in communication and information technology.

·     The invention of lasers and masers.

·     The ability to explain the structure of the atom nucleus.

·     The ability to explain the mechanical and thermal properties of solids.

·     It gave chemistry a firm base and explained chemical bonding. Molecular biology and genetic engineering have also been made possible.

·     Processes in astrophysics such as the physics of stars can be explained using quantum mechanics.

·     Theories surrounding black holes can be explained using quantum mechanics.

In terms of what the future has in store for quantum physics, there are many possible directions. Superconductors and genetic engineering will certainly play a big role in society in the future as well as the area of telecommunications.

But quantum mechanics also has some more far reaching consequences. One such application of quantum physics is in quantum teleportation. Whilst scientists believe that human teleportation is around a century away yet, super fast quantum computers will begin to appear on the shelves over the next decade.

Despite all the possible applications of quantum physics, there is still much work to be done to get some of the above mentioned applications part of mainstream society.

 


Scientist by Scientist:

 

Johannes Rydberg:

 

Hydrogen Line Spectrums:

1900 - Johannes Rydberg, a Swedish Physicist, refined the expression for observed hydrogen line spectrums. However, at this time the phenomenon was still unexplainable. What Rydberg was witnessing was the Balmer series of hydrogen. The Balmer series was the spectra of lines consisting of visible light with transitions to the first excited state (n=2).

 

Contribution:

Rydberg was the one who gave us the first glimpse into the hydrogen spectrum. Without it, the rest of the spectrum may not have been discovered till a much later date.

 

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Ernest Rutherford

 

Alpha Particle Nature:

1903 - Ernest Rutherford, a New Zealand physicist, establishes the fact that alpha particles have a positive charge. This allowed for later scientists to establish alpha particles as helium nuclei.

 

Alpha Particles:

1909 - Ernest Rutherford and Thomas Royds demonstrated that alpha particles are doubly ionized helium atoms. This discovery would not have been made possible except for Rutherford's 1903 work on the nature of an alpha particle.

 

Geiger-Marsden Experiment:

1909 - From Rutherford's above work, Hans Geiger and Ernest Marsden undertook the Geiger-Marsden experiment whereby different metal foils were bombarded with alpha particles.

According to the prevailing "Plum pudding" model of the time, all the alpha particles should have been deflected off but only some were reflected.

This result meant that the "plum pudding" model of the atom was incorrect but it wasn't until 1911 that this result was explained.

 

Rutherford's Model of the Atom:

1911 - Following the disproven "plum pudding" model, Rutherford set out to propose his own model of the atom. Based on the results of the Geiger-Marsden experiment, he postulated that since only some alpha particles were deflected, the atom must be mainly empty space.

He concluded that most of the atom's mass was located in a tiny centre, the nucleus, and electrons were held in orbits surrounding this nucleus by electrostatic attraction.

But his new model was not fool proof. The main problem surrounding his model was that based on his predictions, electrons should radiate electromagnetic energy and rapidly spiral into the nucleus.

However, despite its obvious problems, the model provided the base for Bohr's work a few years later.

 

Protons in the Nucleus:

1914 - Ernest Rutherford proposed that the nucleus, which was known to be positively charged, contained protons.

 

Prediction of the Neutron:

1920 - Due to the fact that there was a mass difference in what an atom should weigh and its actual mass, Ernest Rutherford concluded that the nucleus of a atom contained some particle that had mass but no charge. He theoretically predicted the existence of the neutron.

This prediction later led to James Chadwick's confirmation of the existence of neutrons in 1932.

 

Contribution:

Rutherford's main contributions to physics was in the development of the model of an atom. He also worked with beta decay and produced his own model of the atom in 1911. He was also the one who predicted the existence of neutrons.

 

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Albert Einstein

 

Einstein's Theory of Special Relativity:

1905 - German born, Swiss/American physicist Albert Einstein released his theory of special relativity. Prior to this, the photoelectric effect required explaining. The photoelectric effect is the emission of electrons from matter upon the absorption of electromagnetic radiation. Einstein explained this by proposing that light consisted of discrete quantized bundles of energy. These were later called photons.

He also determined the mass-energy equivalence formula, and this became one of the most well known equations of all time.

E = mc2

 

He also stated that the speed of light was constant for all observers and that it was independent of its source.

The year of 1905 was later regarded as his "wonderful" year as it was the year he began to unravel more mysteries of physics than any other scientist.

 

Conservation of energy-momentum:

1916 - Albert Einstein develops the theory for the conservation of momentum-energy for general relativity. He stated that momentum and energy are intertwined just as space and time are.

From this it follows that mass, energy and momentum will cause the space-time continuum to be curved.

 

Stimulated Radiation Emission:

1917 - Albert Einstein introduces the idea of stimulated radiation emission. This idea had implications in science for the future as stimulated radiation emission is what makes lasers possible.

 

Bose-Einstein Statistics:

1924 - Satyenda Nath Bose and Albert Einstein combined together to find a new way to count quantum particles. This later became known as Bose-Einstein statistics. They also predicted that extremely cold atoms should condense into a single quantum state. This later became known as the Bose-Einstein condensate.

 

Contribution:

Often regarded as the greatest physicist of all time, Albert Einstein's theory of special relativity laid the foundation for the space-time continuum to be understood. He was the one who began to realise the deeper implications of what was occurring on a molecular level.

 

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Niels Bohr

 

Bohr's Model of the Atom:

1913 - Following on from the model developed by Ernest Rutherford, Danish physicist Niels Bohr developed his own model of the atom. He followed on from Rutherford's idea that electrons orbited the nucleus but also stated that the chemical properties of an element were largely due to its electron configuration.

Bohr also introduced the idea that an electron could drop from a higher energy orbit to a lower one, emitting a photon of discrete energy. This was the main reason for its success, the fact that it could explain the spectral lines of hydrogen observed by Rydberg in 1900.

Bohr's model would not have been made possible without Rutherford's model before him and knowledge of the hydrogen spectrum.

A success of Bohr's model was that an equation was developed that could predict the wavelengths of hydrogen spectrum lines:

 

The model also correctly predicted the ionisation energy for hydrogen and predicted the existence of other series in the spectrum (even though they had not yet been discovered).
However, there was still limitations with the model. These included:

  • ·        The Bohr model of the atom was only able to be exclusively applied to hydrogen. It failed to explain the behaviour of any atoms that contained more than one electron.

  • ·        The Bohr model was unable to explain the observed trend that some spectral lines were more intense than others in the spectrum of hydrogen. In other words, it failed to explain why the hydrogen spectrum was inconsistent.

  • ·        When the individual spectral lines were examined closely it was found that they were not solid lines of emitted light or a narrow range of frequencies emitted from the atom, but that they were in fact made up of a number of hyperfine spectral lines. This could not be explained by the Bohr model of the atom.

  • ·        The Bohr model failed to explain the observation why a discharge tube, when placed in a magnetic field, caused the spectral lines to be split into several finely separated but individual lines. This became known as the Zeeman Effect. This implied the energy levels were split which was unacceptable to the concept of metastable orbits or energy levels in the Bohr model.

  • ·        The model itself is a mixture of classical physics and quantum physics and this is a problem in itself.

 

Contribution:

Bohr is regarded as the one who first began to understand the spectrum of hydrogen during his development of his model of the atom. He also helped confirm the wave-particle duality.

 

Back to Top


James Chadwick

 

Continuous Primary Beta Spectrum:

1914 - Sir James Chadwick, and English physicist, showed that the primary beta spectrum is continuous but contains an energy anomaly.

 

Strong Nuclear Interaction:

1921 - Due to the fact that the gravitational attraction of particles in the nucleus was not sufficient enough to hold a nucleus together and the fact that based on what was known at the time, a nucleus should fly apart, James Chadwick and E.S. Bieler conclude that some strong force holds a nucleus together. They called this force 'strong nuclear interaction.'

 

Discovery of the Neutron:

1932 - James Chadwick discovered the neutron. After years of predicted existence since being put forward in 1920 by Ernest Rutherford, the final frontier in terms of atomic understanding was complete and this discovery marked the end of the development of quantum physics but the beginning of its wider reach.

 

Contribution:

He was the one who proposed the strong nuclear force and also is credited with the discovery of the nucleus. Chadwick is regarded as the person who ended the development of quantum physics and started its wider impact.

 

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Louis de Broglie

 

Wave-Particle Duality:

1923 - French nobleman and physicist, Louis de Broglie, concluded that because no-one had successfully proven light was a wave or a particle, all particles must have some wave-like properties and vice versa.

His greatest achievement was to take this idea and development it mathematically into a formula. The de Broglie wavelength of a particle could be expressed by:

However, de Broglie had no experimental results to back up his conclusions and so it was not readily accepted.

 

Contribution:

He was the one who converted a qualitative theory of the dual nature of light into a mathematical expression.

 

Back to Top


Wolfgang Pauli

 

Quantum Exclusion Principle:

1925 - Wolfgang Pauli, an Austrian physicist, is most noted for his work on the quantum exclusion principle. He also explained the previously unexplainable Zeeman effect.

Pauli stated that electrons, known as fermions in his principle, are unable to occupy the same quantum state. As a result of this electrons 'pile on top' of one another and this can produces phenomena such as the Zeeman effect.

Pauli used Bohr's model of the atom that electrons were contained in shells and realised that by adding a fourth quantum number to where there was only three before, he could explain the maximum number of electrons in each shell.

The exclusion principle provided the reason as to why electrons were arranged in shells of 2, 8, 18, etc.

 

Contribution:

Pauli's work on the exclusion principle helped us to understand the Zeeman effect and also aided chemistry by explaining why the shell configurations are 2, 8, 18, etc.

 

Back to Top


Werner Heisenberg

 

Matrix Mechanics:

1925 - German physicists Werner Heisenberg, Max Born and Pascual Jordan successfully developed matrix mechanics. Matrix mechanics was the first version of quantum mechanics and lead to the development of quantum field theory. They built a 'coherent mathematical framework' to which quantum physics could be applied.

From this, Wolfgang Pauli applied matrix mechanics to the hydrogen atom and successfully derived Balmer's equation and Rydberg's constant.

 

Heisenberg's Uncertainty Principle:

1927 - Werner Heisenberg develops his uncertainty principle. Heisenberg showed that uncertainty is an inherent property of quantum mechanics. He reasoned that there were pairs of quantities that could not be determined simultaneously. He stated that if a particle's exact position is known, its momentum cannot be known accurately and vice versa.

This is represented by Heisenberg's Uncertainty Principle where ∆x and ∆p are inherent uncertainties in position and momentum:

 

Contribution:

Heisenberg's greatest achievement was his matrix mechanics, which allowed a mathematical approach to quantum physics, and his uncertainty principle, which allowed us to get a better understanding of the relationship between position and momentum.

 

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Enrico Fermi

 

Fermi-Dirac Statistics:

1926 - Enrico Fermi and Paul Dirac find a second method to count quantum particles. The became known as Fermi-Dirac statistics and opened the way for solid-state physics. Through this, Fermi discovers the spin-statistics connection.

 

Contribution:

Fermi's contribution may seem small but without his efforts, solid state physics may not have been possible.

 

Back to Top


Clinton Davisson

 

Wave-like Nature of Electrons:

1927 - Clinton Davisson and Lester Germer  confirmed the wavelike nature of an electron independently of George Paget Thomson, who did likewise. They did this by verifying the electron diffraction of a crystal.

Davisson & Germer were actually trying to study the reflection of electrons from a nickel surface. However, there was a crack in the vacuum tube they were using and as a result the nickel surface oxidised. They attempted to remove the oxidisation by heating, but this recrystallised the surface. When they fired electrons at it now, the electrons were diffracting. Since diffraction is a wave property they had almost inadvertently proven de Broglie's theory.

 

Contribution:

Davisson finally confirmed what had been theorised, that electrons acted as both a wave and a particle. This helped further understand the hydrogen spectrum.

 

Back to Top


Lester Germer

 

Wave-like Nature of Electrons:

1927 - Clinton Davisson and Lester Germer  confirmed the wavelike nature of an electron independently of George Paget Thomson, who did likewise. They did this by verifying the electron diffraction of a crystal.

Davisson & Germer were actually trying to study the reflection of electrons from a nickel surface. However, there was a crack in the vacuum tube they were using and as a result the nickel surface oxidised. They attempted to remove the oxidisation by heating, but this recrystallised the surface. When they fired electrons at it now, the electrons were diffracting. Since diffraction is a wave property they had almost inadvertently proven de Broglie's theory.

 

Contribution:

Davisson finally confirmed what had been theorised, that electrons acted as both a wave and a particle. This helped further understand the hydrogen spectrum.

 

Back to Top

 

 

  Last Updated 06/08/2007